Sulfur-Containing Polymers Prepared from Fatty Acid-Derived Monomers: Application of Atom-Economical Thiol-eneThiol-yne Click Reactions and Inverse Vulcanization Strategies by Ashlyn D. Smith Andrew G. Tennyson & Rhett C. Smith
Author:Ashlyn D. Smith, Andrew G. Tennyson & Rhett C. Smith
Format: pdf
Tags: This paper is review with 119 references. Approaches to supplant currently used plastics with materials made from more sustainably-sourced monomers is one of the great contemporary challenges in sustainable chemistry. Fatty acids are attractive candidates as polymer precursors because they can be affordably produced on all inhabited continents, and they are also abundant as underutilized by-products of other industries. In surveying the array of synthetic approaches to convert fatty acids into polymers, those routes that produce organosulfur polymers stand out as being especially attractive from a sustainability standpoint. The first well-explored synthetic approach to fatty acid-derived organosulfur polymers employs the thiol-ene click reaction or the closely-related thiol-yne variation. This approach is high-yielding under mild conditions with up to 100% atom economy and high functional group tolerance. More recently, inverse vulcanization has been employed to access high sulfur-content polymers by the reaction of fatty acid-derived olefins with elemental sulfur. This approach is attractive not only because it is theoretically 100% atom economical but also because elemental sulfur is itself an underutilized by-product of fossil fuel refining. The thiol-ene, inverse vulcanization, and mechanistically-related thiol-yne and classic vulcanization are therefore discussed as promising routes to access polymers and composites from fatty acid-derived precursors., sustainable polymers; fatty acids; thiol-ene; inverse vulcanization
Download
This site does not store any files on its server. We only index and link to content provided by other sites. Please contact the content providers to delete copyright contents if any and email us, we'll remove relevant links or contents immediately.
Concrete | Extraction & Processing |
Fracture Mechanics | Materials Science |
Metallurgy | Polymers & Textiles |
Strength of Materials | Testing |
Whiskies Galore by Ian Buxton(40511)
Introduction to Aircraft Design (Cambridge Aerospace Series) by John P. Fielding(32346)
Small Unmanned Fixed-wing Aircraft Design by Andrew J. Keane Andras Sobester James P. Scanlan & András Sóbester & James P. Scanlan(32148)
Craft Beer for the Homebrewer by Michael Agnew(17463)
Turbulence by E. J. Noyes(7058)
The Complete Stick Figure Physics Tutorials by Allen Sarah(6648)
Kaplan MCAT General Chemistry Review by Kaplan(6066)
The Thirst by Nesbo Jo(5794)
Bad Blood by John Carreyrou(5782)
Learning SQL by Alan Beaulieu(5424)
Weapons of Math Destruction by Cathy O'Neil(5046)
Man-made Catastrophes and Risk Information Concealment by Dmitry Chernov & Didier Sornette(4749)
iGen by Jean M. Twenge(4708)
Digital Minimalism by Cal Newport;(4568)
Life 3.0: Being Human in the Age of Artificial Intelligence by Tegmark Max(4520)
Audition by Ryu Murakami(4107)
1,001 ASVAB Practice Questions For Dummies by Powers Rod(4046)
Electronic Devices & Circuits by Jacob Millman & Christos C. Halkias(4041)
Pale Blue Dot by Carl Sagan(4017)