Mechanosynthesis of Diaminobiphenyls-Based Schiff’s Bases as Simple Probes for the Naked-Eye Detection of Cyanide Ion by unknow

Author:unknow
Format: pdf
Tags: Cyanide ions are known to be lethal for insects and mammals and harmful for the environment, and new methods for their selective detection are in high demand. Herein, the mechanosynthesis of simple Schiff’s bases-based probes S1–S3 for visual detection of CN- anion is reported. These probes were obtained by means of a reaction between isomeric 4,4-, 3,3- and 2,2-diaminobiphenyls and 4-nitrobenzaldehyde under ball milling conditions. The probes showed high selectivity and sensitivity toward CN- anion via a dramatic “yellow-to-dark purple’’ color change with a detection limit of 26 103, 8.7 103 and 14 103 ppm for S1–S3, respectively. The proposed mechanism of the detection suggests the deprotonation of a proton from an imine moiety, followed by the formation of charge transfer complexes (CTC)., mechanosynthesis; Schiff bases; cyanide ion detection; color change


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