Theory of Liquids and Other Disordered Media by Walter Schirmacher

Author:Walter Schirmacher
Language: eng
Format: epub
Publisher: Springer International Publishing, Cham

(6.13)

where the second term is again the free energy of squeezing. Minimizing this expression with respect to D we obtain (with A = 1)

(6.14)

from which follows

(6.15)

We see that, as to be expected, the free energy of adsorption decreases, and the layer thickness increases with increasing temperature.

Another quantity of interest is the radial pair correlation function of monomers which is just the counter part of this quantity in simple liquids. In simple liquids g(r) was defined in such a way that for large r the integral

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