Hydrothermal Carbonization of Sugarcane Tip (Saccharum officinarum L.) for Pb (II) Removal: Synthesis, Characterization, and Adsorption Equilibrium by unknow

Author:unknow
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Tags: Water contamination by heavy metals, particularly lead, derived from industrialization, climate change, and urbanization, represents a critical risk to human health and the environment. Several agricultural biomass residues have demonstrated efficacy as contaminant adsorbents. In this context, the study aimed to evaluate the potential of sugarcane tip (ST) waste biomass treated by hydrothermal carbonization (HTC) to produce hydrochar as an adsorbent material for Pb2+ in aqueous solutions. Samples were synthesized from the waste biomass at temperatures of 180 C, 215 C, and 250 C, with a constant pressure of 6 MPa. Aqueous solutions of Pb2+ were prepared at concentrations of 10, 25, 50, 75, and 100 mg/L. Each solution was stirred at 1 g of hydrochar at 150 rpm, 25 C, and pH 5 for 15 to 120 min. The solutions were filtered and stored at 4 C for flame atomic absorption spectrophotometry analysis. In all cases, equilibrium was reached rapidly—within 15 min or less—as indicated by the stabilization of qt values over time. At an initial concentration of 100 mg L-1, the highest equilibrium uptake was observed for the hydrochar synthesized at ST HTC 180 C (4.90 mg g-1), followed by 4.58 mg g-1 and 4.52 mg g-1 for ST HTC 215 C and ST HTC 250 C, respectively. For the ST HTC 180 C, the Sips model provided the best correlation with the experimental data, exhibiting a high maximum capacity (qmax = 240.8 mg g-1; Ks = 0.007; n = 1.09; R2 = 0.975), which reinforces the heterogeneous nature of the material’s surface. Hydrothermal synthesis increased the amount of acidic active sites in the ST HTC 180 C material from 1.3950 to 3.8543 meq g-1, which may influence the electrical charge of the Pb2+ adsorption process. HTC-treated sugarcane tip biomass represents a promising alternative for the synthesis of adsorbent materials, contributing to water remediation and promoting the circular economy by sustainably utilizing agricultural waste., biomass; circularity; sugarcane; adsorption; hydrochar; waste; remediation


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