Synthesis and Structure of N-(1-(Bromomethyl)-7,7-dimethylbicyclo[2.2.1]heptan-2-yl)benzenesulfonamide by Ivan A. Garagan Mikhail Yu. Moskalik Irina V. Sterkhova & Anton S. Ganin
![Synthesis and Structure of N-(1-(Bromomethyl)-7,7-dimethylbicyclo[2.2.1]heptan-2-yl)benzenesulfonamide by Ivan A. Garagan Mikhail Yu. Moskalik Irina V. Sterkhova & Anton S. Ganin](https://img.ebook-hunter.org/img/Synthesis%20and%20Structure%20of%20N-%281-%28Bromomethyl%29-7%2C7-dimethylbicyclo%5B2.2.1%5Dheptan-2-yl%29benzenesulfonamide%20by%20Ivan%20A.%20Garagan%20Mikhail%20Yu.%20Moskalik%20Irina%20V.%20Sterkhova%20%26%20Anton%20S.%20Ganin.jpg)
Author:Ivan A. Garagan, Mikhail Yu. Moskalik, Irina V. Sterkhova & Anton S. Ganin
Format: pdf
Tags: A new bicyclic sulfonamide derivative, N-(1-(bromomethyl)-7,7-dimethylbicyclo[2.2.1]heptan-2-yl)benzenesulfonamide, was synthesized in the reaction of benzenesulfonamide and camphene in the presence of N-bromosuccinimide in acetonitrile. The proposed mechanism of investigated reaction involves the Wagner–Meerwein rearrangement stage. 3-(Bromomethylene)-2,2-dimethylbicyclo[2.2.1]heptane was isolated as a minor product. The products were characterized by IR, NMR spectroscopy, X-ray diffraction analysis, HRMS and elemental analysis data., camphene; benzenesulfonamide; bromosulfonamidation; rearrangement; oxidative reactions
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