Elements of Statistical Thermodynamics by Nash Leonard K.;

Author:Nash, Leonard K.;
Language: eng
Format: epub
ISBN: 1894549
Publisher: Dover Publications
Published: 2012-10-05T16:00:00+00:00

Evaluations of ztry and ztrz yield corresponding expressions in terms of Ly and Lz respectively. For the complete translational partition function (ztrans) we can then write

Or, since the product of the linear dimensions of the box must equal the volume (V) thereof,

Now at last we can supply the long-promised demonstration that β = 1/kT, where T symbolizes a temperature easily measurable on the familiar ideal-gas scale. On the strength of equation (14), we substitute in equation (f) on p. 60, to find

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