Modern Organoaluminum Reagents by Simon Woodward & Samuel Dagorne
Author:Simon Woodward & Samuel Dagorne
Language: eng
Format: epub
Publisher: Springer Berlin Heidelberg, Berlin, Heidelberg
Traditionally, alkenes are hydroaluminated using inorganic aluminum hydrides (AlH3, AlHCl2, AlHBr2, LiAlH4, NaAlH4) or organoaluminum reagents represented most often by diisobutylaluminum hydride (iBu2AlH), diethylaluminum hydride (Et2AlH), triisobutylaluminum (Bu3Al), and diisobutylaluminum chloride (iBu2AlCl) [10]. The hydride alanes iBu2AlH, iBu3Al, and LiAlH4 are most popular as hydroaluminating reagents. The utilization of aluminum dialkylamides, cycloalumoxane, and diisobutylaluminum phenoxide as hydroaluminating reagents was reported [10].
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